G. V. Svetlakov, Z. M. Rubanov, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2026, e70475
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Overcoming the Reactivity Challenge in Radical Fluoroalkylation of N-Phenylhydrazones: A Divergent Approach for Substrates Derived from Aliphatic and Aromatic Aldehydes
Novel Synthesis of Benzo[e][1,2,4]triazines via Cyclocondensation of Azooximes
gem-Difluorinated Phosphonium Salts as Sources of Difluoroalkyl Radicals
A. L. Trifonov, A. D. Dilman
Chem. Rec. 2026, e70150
Fluorinated Alkyl Zinc Bromides in Cu/Photoredox Promoted Decarboxylative Cross-Coupling
S. A. Imaev, A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2026, 7, e70389
Photoinduced Synthesis of gem-Difluorinated Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
Org. Lett. 2026, 28, 573–577
Photoinduced hydrofluoroalkylation of alkenes
V. S. Kostromitin, V. V. Levin, A. D. Dilman
Coord. Chem. Rev. 2026, 548, 217189
Light-Mediated Ring-Opening Functionalization of Epoxides via a Fluorinated Thiolate Mediator
A. G. Savchenko, M. O. Zubkov, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10831–10835
Exploring the Radical Addition to Sydnones: A Gateway to Perfluoroalkyl-Substituted Pyrazoles
Z. M. Rubanov, D. S. Koltun, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10241–10245
Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride
S. S. Lunkov, E. V. Malakhova, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 9506–9510
Photocatalytic Fluoroalkylation of Derivatives of 3-Aminopyrazole
D. S. Koltun, V. V. Levin, A. D. Dilman
Russ. J. Org. Chem. 2025, 61, 1076–1080
Synthesis of gem-Difluorinated N-Boc Amines from N-Boc Imines via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
J. Org. Chem. 2025, 90, 10148–10153
Light Promoted Vinylogous Arbuzov Reaction with Electron Deficient Alkyl Halides
V. S. Kostromitin, V. I. Supranovich, A. D. Dilman
Org. Lett. 2025, 27, 7106–7110
Copper/Bis(imine)-Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
L. A. Peresypkin, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2025, 28, e202500393
Synthesis and Evaluation of Silicon-Containing Acridine Photocatalysts
L. O. Kupriyanets, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
ChemPhotoChem 2025, e202500138
Radical 1,2-fluoroalkylation/stannylation of terminal alkynes
V. I. Supranovich, A. D. Dilman
J. Fluorine Chem. 2025, 283, 110422
Unlocking the reactivity of the C–In bond: alkyl indium reagents as a source of radicals under photocatalytic conditions
A. A. Gladkov, V. V. Levin, D. Y. Cheboksarov, A. D. Dilman
Chem. Sci. 2025, 16, 5623-5631
Direct C1 homologation of carboxylic acids: free radical approach enabled by acridine catalysis
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2025, 12, 2255-2259
Photocatalytic anti-Markovnikov addition of carboxylic acids to alkenes: an ionic mechanism under radical conditions
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Chem. Front. 2025, 12, 1918-1926
Light-Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Chem. Rec. 2025, 25, e202400194
Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group
A. L. Trifonov, A. D. Dilman
Org. Lett. 2024, 26, 10589–10593
Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole-Derived Sulfide Reagent
A. O. Sorokin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 5171-5175
Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids
Z. M. Rubanov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2024, 34, 673-675
Sodium Hypophosphite as a Halogen Atom Transfer (XAT) Agent under Photocatalytic Conditions
E. V. Malakhova, V. S. Kostromitin, D. Y. Cheboksarov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 12812–12821
Photoredox Activation of Fluorinated Organozinc Reagents: Hydrofluoroalkylation of Unactivated and Electron Deficient Alkenes
A. G. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 11826–11835
Photocatalytic Functionalization of Alkenes Enabled by Polyfluoroaryl Migration
A. G. Savchenko, M. O. Zubkov, J. Hu, A. D. Dilman
ChemPhotoChem 2024, 8, e202400159
Synthesis of 3-(2,3,5,6-tetrafluoropyridinylthio)pyrazoles from 3-aminopyrazoles
D. S. Koltun, A. D. Dilman
Mendeleev Commun. 2024, 34, 531–532
A photocatalytic method for the generation of the 1,1,1,3,3,3-hexafluoroisopropyl radical
S. S. Lunkov, V. S. Kostromitin, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 4762-4768
Photoinduced radical alkylation of aldehydes with potassium alkyltrifluoroborates
K. A. Zhilyaev, M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 3988-3996
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
V. I. Supranovich, V. V. Levin, A. D. Dilman
Org. Lett. 2024, 26, 4537–4541
Complexes of Borane and 1,3,5-Triazinane-Derived Carbenes
V. O. Smirnov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 11, 2483-2488
Синтез N-(иминил)пиридиниевых солей из гидразонов по реакции Цинке
Е. А. Ильин, В. О. Смирнов, А. Д. Дильман
Известия Академии наук. Серия химическая, 2024, 73, 1297-1302
Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Lett. 2024, 26, 3174–3178
Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond
M. O. Zubkov, A. D. Dilman
Chem. Soc. Rev. 2024, 53, 4741 - 4785
Tetrafluoropyridinyl Thiolate as a Tool for Enabling Photoredox Alkylation of 1,2,4-Oxadiazoles
A. E. Frumkin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 3505-3510
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Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion
E. V. Malakhova, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 2829-2833
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Direct conversion of carboxylic acids to free thiols via radical relay acridine photocatalysis enabled by N–O bond cleavage
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Chem. Sci. 2024, 15, 644-650
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One-Pot Transformation of Aldehydes to Ketones via Minisci-Type Reaction of Imines
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Lett. 2023, 25, 8751–8755
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gem-Difluoroolefination of Amides
A. L. Trifonov, A. D. Dilman
Chem. Eur. J. 2023, 29, e202303144
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Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides
A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 19, 3387-3391
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Photocatalytic Reaction of Aryl Halides with Tin(II) Acetate to Generate Arylstannane(IV) Reagents
A. A. Zemtsov, V. I. Supranovich, V. V. Levin, A. D. Dilman
ACS Catal. 2023, 13, 12766–12773
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C–F Activation of Fluorinated Esters Using Photocatalytically Generated Diaminoalkyl Radical
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Org. Lett. 2023, 25, 6598–6602
Zinc Chelate Complexes of N-Acyl Hydrazones as Substrates for Addition of Alkyl and Fluorinated Radicals
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 15, 2636-2642
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Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System
V. S. Kostromitin, V. V. Levin, A. D. Dilman
Catalysts. 2023, 13, 1126
Visible light-induced thiocyanation of gem-difluorinated phosphonium salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
Mendeleev Commun. 2023, 33, 491-493
https://doi.org/10.1016/j.mencom.2023.06.016
BF2-Chelates of N-Acylhydrazones as Versatile Coupling Partners in Photoredox Promoted Reactions
Z. M. Rubanov, V. I. Supranovich, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2023, 26, e202300247
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Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α-(Trifluoromethyl)styrenes
A. G. Savchenko, M. O. Zubkov, V. A. Kokorekin, J. Hu, A. D. Dilman
ChemCatChem 2023, 15, e202300505
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Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine
S. L. Lunkov, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2023, 33, 387–389
https://doi.org/10.1016/j.mencom.2023.04.028
Dual Photoredox/Copper Catalyzed Fluoroalkylative Alkene Difunctionalization
V. S. Kostromitin, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 6252–6262
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Visible-Light Promoted Radical Fluoroalkylation of O- and N-Substituted Alkenes
V. V. Levin, A. D. Dilman
Chem. Rec. 2023, 23, e202300038
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Aminals as powerful XAT-reagents: activation of fluorinated alkyl chlorides
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Chem. Sci. 2023, 14, 3229–3234
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Photoredox Promoted Barbier-Type Reaction of Alkyl Iodides with N-Alkyl and N-Aryl Imines
A. A. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 1260–1269
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Фотокаталитические реакции фторалкилиодидов с алкенами
Г. Н. Чернов, В. В. Левин, А. Д. Дильман
Изв. Акад. наук., Сер. хим. 2023, 72, 61-72
Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes
V. S. Kostromitin, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 6523–6531
Light-Promoted Dearylation of Perfluorinated Aryl Sulfides with N-Heterocyclic Carbene–Borane
L. I. Panferova, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Lett. 2022, 24, 8559–8563
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Novel fluorescent difluoroboryl chelate complexes derived from N-benzothiazolyl hydrazones
Z. M. Rubanov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Tetrahedron Lett. 2022, 108, 154154
Generation of fluoro(thio)carbenes from Me3SiCF2SAr
E. A. Ilin, V. O. Smirnov, A. D. Dilman
J. Fluorine Chem. 2022, 261-262, 110025
Preparation and Evaluation of Sterically Hindered Acridine Photocatalysts
K. A. Zhilyaev, D. L. Lipilin, M. D. Kosobokov, A. I. Samigullina, A. D. Dilman
Adv. Synth. Catal. 2022, 364, 3295–3301
Photocatalyzed Decarboxylative Thiolation of Carboxylic Acids Enabled by Fluorinated Disulfide
M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Lett. 2022, 24, 2354–2358
Allylic substitution reactions with fluorinated nucleophiles
A. A. Zemtsov, V. V. Levin, A. D. Dilman
Coord. Chem. Rev. 2022, 459, 214455
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Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates
V. I. Supranovich, A. D. Dilman
Catalysts 2021, 11, 1555
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Photoredox Activation of Organozinc Reagents: Barbier-Type Reaction of Alkyl Halides with α-(Trifluoromethyl)styrenes
A. A. Gladkov, G. N. Chernov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Org. Lett. 2021, 23, 9645-9648
Boron Chelates Derived from N-Acylhydrazones as Radical Acceptors: Photocatalyzed Coupling of Hydrazones with Carboxylic Acids
I. A. Dmitriev, V. V. Levin, A. D. Dilman
Org. Lett. 2021, 23, 8973-8977
Photocatalytic Atom-Transfer Radical Addition of Activated Chlorides to Alkenes
V. S. Kostromitin, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2021, 363, 5336–5340
Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene
Org. Lett. 2021, 23, 6977–6981
One-pot synthesis of α-trifluoromethylstyrenes from aryl ketones and the Ruppert–Prakash reagent
Mendeleev Commun. 2021, 31, 684–685
Радикальная функционализация гем-дифторалкенов
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Reaction of (bromodifluoromethyl)trimethylsilane with HMPA: Structural studies
J. Fluorine Chem. 2021, 250, 109881
Generation of Alkyl Radicals from Thiols via Zinc Thiolates: Application for the Synthesis of gem-Difluorostyrenes
Adv. Synth. Cat. 2021, 363, 2888–2892
Light-Mediated Sulfur–Boron Exchange
Org. Lett. 2021, 23, 3919-3922
Photoredox Catalyzed Dealkylative Aromatic Halogen Substitution with Tertiary Amines
Molecules 2021, 26, 3323
Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system
Chem. Commun. 2021, 57, 5219-5222
Visible-Light-Promoted Reversible Sulfide/Iodide Exchange in Fluoroalkyl Sulfides Enabled by Electron Donor-Acceptor Complex Formation
ChemPhotoChem 2021, 5, 565-570
All-carbon phosphoranes via difluorocarbene trapping
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Photoredox Fluoroalkylation of Hydrazones in Neutral and Reductive Modes
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Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent
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Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds
Angew. Chem. Int. Ed. 2021, 60, 2849–2854
Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate
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Synthesis of tetrafluorinated piperidines from nitrones via a visible-light-promoted annelation reaction
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Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization
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ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping
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Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation
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Photoredox Fluoroalkylation of Arylidene and Alkylidene Amidrazones
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A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes
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Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
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Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical Addition Reaction
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Photoredox Reaction of 2-Mercaptothiazolinium Salts with Silyl Enol Ethers
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Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst
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Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction
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Tetrahedron 2018, 74, 7136–7142
Photocatalytic Reductive Fluoroalkylation of Nitrones
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J. Fluorine Chem. 2013, 154, 73–79
Nucleophilic fluoroalkylation of (bromomethyl)pinacolborane using silicon reagents
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Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions
J. Org. Chem. 2012, 77, 2080-2086
Three-component reactions of CF3-substituted boranes, ethyl diazoacetate and imines
Tetrahedron Lett. 2012, 53, 6216-6218
Nucleophilic Pentafluorophenylation of Nitroalkenes
Synthesis 2012, 44, 2436-2440
Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
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Reactions of CF3-substituted boranes with α-diazocarbonyl compounds
Tetrahedron Lett. 2011, 52, 5259-5263
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Tetrahedron Lett. 2011, 52, 281-284
Nucleophilic Trifluoromethylation of C=N Bonds
Eur. J. Org. Chem. 2011, 831-841
Reactions of fluorinated silanes with 2-nitrocinnamates
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Reaction of Baylis–Hillman Adducts with Fluorinated Silanes
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Chelation-assisted pentafluorophenylation of oximes
Mendeleev Commun. 2010, 20, 220-222
Hydroxyl-directed trifluoromethylation of hydrazones
Mendeleev Commun. 2009, 19, 141-143
Nucleophilic trifluoromethylation of arylidene Meldrum's acids
Tetrahedron Lett. 2009, 50, 2998-3000
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Tetrahedron Lett. 2009, 50, 2994-2997
Reaction of the Ruppert-Prakash reagent with perfluorosulfonic acids
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Трифторметилирование амидной группы
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Tetrahedron Lett. 2008, 49, 4352
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Tetrahedron Lett. 2008, 49, 310
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Eur. J. Org. Chem. 2008, 5226
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Trifluoromethylation of N-Benzoylhydrazones
Реакция формамидов с трис(пентафторфенил)фторсиланом
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Trifluoromethylation of Salicyl Aldimines
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Tetrahedron Lett. 2006, 47, 6217
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Tetrahedron Lett. 2006, 47, 8959
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Mendeleev Commun., 2007, 10
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
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Tetrahedron Lett. 2005, 46, 3729
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Tetrahedron Lett. 2004, 45, 3741
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Tetrahedron Lett. 2004, 45, 3741