G. V. Svetlakov, Z. M. Rubanov, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2026, e70475
https://doi.org/10.1002/ejoc.70475
Overcoming the Reactivity Challenge in Radical Fluoroalkylation of N-Phenylhydrazones: A Divergent Approach for Substrates Derived from Aliphatic and Aromatic Aldehydes
Novel Synthesis of Benzo[e][1,2,4]triazines via Cyclocondensation of Azooximes
gem-Difluorinated Phosphonium Salts as Sources of Difluoroalkyl Radicals
A. L. Trifonov, A. D. Dilman
Chem. Rec. 2026, e70150
Fluorinated Alkyl Zinc Bromides in Cu/Photoredox Promoted Decarboxylative Cross-Coupling
S. A. Imaev, A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2026, 7, e70389
Photoinduced Synthesis of gem-Difluorinated Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
Org. Lett. 2026, 28, 573–577
Photoinduced hydrofluoroalkylation of alkenes
V. S. Kostromitin, V. V. Levin, A. D. Dilman
Coord. Chem. Rev. 2026, 548, 217189
Light-Mediated Ring-Opening Functionalization of Epoxides via a Fluorinated Thiolate Mediator
A. G. Savchenko, M. O. Zubkov, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10831–10835
Exploring the Radical Addition to Sydnones: A Gateway to Perfluoroalkyl-Substituted Pyrazoles
Z. M. Rubanov, D. S. Koltun, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10241–10245
Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride
S. S. Lunkov, E. V. Malakhova, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 9506–9510
Photocatalytic Fluoroalkylation of Derivatives of 3-Aminopyrazole
D. S. Koltun, V. V. Levin, A. D. Dilman
Russ. J. Org. Chem. 2025, 61, 1076–1080
Synthesis of gem-Difluorinated N-Boc Amines from N-Boc Imines via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
J. Org. Chem. 2025, 90, 10148–10153
https://doi.org/10.1021/acs.joc.5c01356
Light Promoted Vinylogous Arbuzov Reaction with Electron Deficient Alkyl Halides
V. S. Kostromitin, V. I. Supranovich, A. D. Dilman
Org. Lett. 2025, 27, 7106–7110
Copper/Bis(imine)-Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
L. A. Peresypkin, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2025, 28, e202500393
Synthesis and Evaluation of Silicon-Containing Acridine Photocatalysts
L. O. Kupriyanets, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
ChemPhotoChem 2025, e202500138
Radical 1,2-fluoroalkylation/stannylation of terminal alkynes
V. I. Supranovich, A. D. Dilman
J. Fluorine Chem. 2025, 283, 110422
Unlocking the reactivity of the C–In bond: alkyl indium reagents as a source of radicals under photocatalytic conditions
A. A. Gladkov, V. V. Levin, D. Y. Cheboksarov, A. D. Dilman
Chem. Sci. 2025, 16, 5623-5631
Direct C1 homologation of carboxylic acids: free radical approach enabled by acridine catalysis
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2025, 12, 2255-2259
Photocatalytic anti-Markovnikov addition of carboxylic acids to alkenes: an ionic mechanism under radical conditions
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Chem. Front. 2025, 12, 1918-1926
Light-Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Chem. Rec. 2025, 25, e202400194
Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group
A. L. Trifonov, A. D. Dilman
Org. Lett. 2024, 26, 10589–10593
Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole-Derived Sulfide Reagent
A. O. Sorokin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 5171-5175
https://doi.org/10.1002/adsc.202400884
Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids
Z. M. Rubanov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2024, 34, 673-675
Sodium Hypophosphite as a Halogen Atom Transfer (XAT) Agent under Photocatalytic Conditions
E. V. Malakhova, V. S. Kostromitin, D. Y. Cheboksarov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 12812–12821
https://doi.org/10.1021/acs.joc.4c01412
Photoredox Activation of Fluorinated Organozinc Reagents: Hydrofluoroalkylation of Unactivated and Electron Deficient Alkenes
A. G. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 11826–11835
https://doi.org/10.1021/acs.joc.4c01623
Photocatalytic Functionalization of Alkenes Enabled by Polyfluoroaryl Migration
A. G. Savchenko, M. O. Zubkov, J. Hu, A. D. Dilman
ChemPhotoChem 2024, 8, e202400159
https://doi.org/10.1002/cptc.202400159
Synthesis of 3-(2,3,5,6-tetrafluoropyridinylthio)pyrazoles from 3-aminopyrazoles
D. S. Koltun, A. D. Dilman
Mendeleev Commun. 2024, 34, 531-532
https://doi.org/10.1016/j.mencom.2024.06.020
A photocatalytic method for the generation of the 1,1,1,3,3,3-hexafluoroisopropyl radical
S. S. Lunkov, V. S. Kostromitin, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 4762-4768
https://doi.org/10.1039/D4QO01023J
Photoinduced radical alkylation of aldehydes with potassium alkyltrifluoroborates
K. A. Zhilyaev, M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 3988-3996
https://doi.org/10.1039/D4QO00741G
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
V. I. Supranovich, V. V. Levin, A. D. Dilman
Org. Lett. 2024, 26, 4537–4541
Complexes of Borane and 1,3,5-Triazinane-Derived Carbenes
V. O. Smirnov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 11, 2483-2488
Synthesis of N-(iminyl)pyridinium salts from hydrazones by the Zincke reaction
E. A. Ilin, V. O. Smirnov, A. D. Dilman
Russ. Chem. Bull. 2024, 73, 1297-1302
Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Lett. 2024, 26, 3174–3178
Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond
M. O. Zubkov, A. D. Dilman
Chem. Soc. Rev. 2024, 53, 4741 - 4785
Tetrafluoropyridinyl Thiolate as a Tool for Enabling Photoredox Alkylation of 1,2,4-Oxadiazoles
A. E. Frumkin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 3505-3510
https://doi.org/10.1002/adsc.202400075
Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion
E. V. Malakhova, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 2829-2833
https://doi.org/10.1039/D4QO00228H
Direct conversion of carboxylic acids to free thiols via radical relay acridine photocatalysis enabled by N–O bond cleavage
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Chem. Sci. 2024, 15, 644-650
https://doi.org/10.1039/D3SC05513B
One-Pot Transformation of Aldehydes to Ketones via Minisci-Type Reaction of Imines
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Lett. 2023, 25, 8751–8755
https://doi.org/10.1021/acs.orglett.3c03764
gem-Difluoroolefination of Amides
A. L. Trifonov, A. D. Dilman
Chem. Eur. J. 2023, 29, e202303144
https://doi.org/10.1002/chem.202303144
Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides
A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 19, 3387-3391
https://doi.org/10.1002/adsc.202300757
Photocatalytic Reaction of Aryl Halides with Tin(II) Acetate to Generate Arylstannane(IV) Reagents
A. A. Zemtsov, V. I. Supranovich, V. V. Levin, A. D. Dilman
ACS Catal. 2023, 13, 12766–12773
https://doi.org/10.1021/acscatal.3c03626
C–F Activation of Fluorinated Esters Using Photocatalytically Generated Diaminoalkyl Radical
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Org. Lett. 2023, 25, 6598–6602
Zinc Chelate Complexes of N-Acyl Hydrazones as Substrates for Addition of Alkyl and Fluorinated Radicals
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 15, 2636-2642
https://doi.org/10.1002/adsc.202300606
Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System
V. S. Kostromitin, V. V. Levin, A. D. Dilman
Catalysts. 2023, 13, 1126
https://doi.org/10.3390/catal13071126
Visible light-induced thiocyanation of gem-difluorinated phosphonium salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
Mendeleev Commun. 2023, 33, 491-493
https://doi.org/10.1016/j.mencom.2023.06.016
BF2-Chelates of N-Acylhydrazones as Versatile Coupling Partners in Photoredox Promoted Reactions
Z. M. Rubanov, V. I. Supranovich, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2023, 26, e202300247
https://doi.org/10.1002/ejoc.202300247
Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α-(Trifluoromethyl)styrenes
A. G. Savchenko, M. O. Zubkov, V. A. Kokorekin, J. Hu, A. D. Dilman
ChemCatChem 2023, 15, e202300505
https://doi.org/10.1002/cctc.202300505
Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine
S. L. Lunkov, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2023, 33, 387–389
https://doi.org/10.1016/j.mencom.2023.04.028
Dual Photoredox/Copper Catalyzed Fluoroalkylative Alkene Difunctionalization
V. S. Kostromitin, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 6252–6262
https://doi.org/10.1021/acs.joc.3c00448
Visible-Light Promoted Radical Fluoroalkylation of O- and N-Substituted Alkenes
V. V. Levin, A. D. Dilman
Chem. Rec. 2023, 23, e202300038
https://doi.org/10.1002/tcr.202300038
Aminals as powerful XAT-reagents: activation of fluorinated alkyl chlorides
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Chem. Sci. 2023, 14, 3229–3234
https://doi.org/10.1039/D3SC00027C
Photoredox Promoted Barbier-Type Reaction of Alkyl Iodides with N-Alkyl and N-Aryl Imines
A. A. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 1260–1269
https://doi.org/10.1021/acs.joc.2c02598
Photocatalytic reactions of fluoroalkyl iodides with alkenes
G. I. Chernov, V. V. Levin, A. D. Dilman
Russ. Chem. Bull. 2023, 72, 61-72
Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes
V. S. Kostromitin, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 6523–6531
Light-Promoted Dearylation of Perfluorinated Aryl Sulfides with N-Heterocyclic Carbene–Borane
L. I. Panferova, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Lett. 2022, 24, 8559–8563
https://doi.org/10.1021/acs.orglett.2c03585
Novel fluorescent difluoroboryl chelate complexes derived from N-benzothiazolyl hydrazones
Z. M. Rubanov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Tetrahedron Lett. 2022, 108, 154154
Generation of fluoro(thio)carbenes from Me3SiCF2SAr
E. A. Ilin, V. O. Smirnov, A. D. Dilman
J. Fluorine Chem. 2022, 261-262, 110025
Preparation and Evaluation of Sterically Hindered Acridine Photocatalysts
K. A. Zhilyaev, D. L. Lipilin, M. D. Kosobokov, A. I. Samigullina, A. D. Dilman
Adv. Synth. Catal. 2022, 364, 3295–3301
Photocatalyzed Decarboxylative Thiolation of Carboxylic Acids Enabled by Fluorinated Disulfide
M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Lett. 2022, 24, 2354–2358
https://doi.org/10.1021/acs.orglett.2c00549
Allylic substitution reactions with fluorinated nucleophiles
A. A. Zemtsov, V. V. Levin, A. D. Dilman
Coord. Chem. Rev. 2022, 459, 214455
https://doi.org/10.1016/j.ccr.2022.214455