Overcoming the Reactivity Challenge in Radical Fluoroalkylation of N-Phenylhydrazones: A Divergent Approach for Substrates Derived from Aliphatic and Aromatic Aldehydes
G. V. Svetlakov, Z. M. Rubanov, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2026, e70475
https://doi.org/10.1002/ejoc.70475
Novel Synthesis of Benzo[e][1,2,4]triazines via Cyclocondensation of Azooximes
A. E. Frumkin, A. D. Dilman
Adv. Synth. Catal. 2026, 10, e70430
https://doi.org/10.1002/adsc.70430
Fluorinated Alkyl Zinc Bromides in Cu/Photoredox Promoted Decarboxylative Cross-Coupling
S. A. Imaev, A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2026, 7, e70389
https://doi.org/10.1002/adsc.70389
Photoinduced Synthesis of gem-Difluorinated Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
Org. Lett. 2026, 28, 573–577
https://doi.org/10.1021/acs.orglett.5c05084
Light-Mediated Ring-Opening Functionalization of Epoxides via a Fluorinated Thiolate Mediator
A. G. Savchenko, M. O. Zubkov, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10831–10835
https://doi.org/10.1021/acs.orglett.5c03458
Exploring the Radical Addition to Sydnones: A Gateway to Perfluoroalkyl-Substituted Pyrazoles
Z. M. Rubanov, D. S. Koltun, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 10241–10245
https://doi.org/10.1021/acs.orglett.5c03398
Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride
S. S. Lunkov, E. V. Malakhova, V. V. Levin, A. D. Dilman
Org. Lett. 2025, 27, 9506–9510
https://doi.org/10.1021/acs.orglett.5c03013
Synthesis of gem-Difluorinated N-Boc Amines from N-Boc Imines via Difluorinated Phosphonium Salts
G. A. Lozhkin, A. L. Trifonov, A. D. Dilman
J. Org. Chem. 2025, 90, 10148–10153
https://doi.org/10.1021/acs.joc.5c01356
Copper/Bis(imine)-Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
L. A. Peresypkin, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2025, 28, e202500393
https://doi.org/10.1002/ejoc.202500393
Synthesis and Evaluation of Silicon-Containing Acridine Photocatalysts
L. O. Kupriyanets, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
ChemPhotoChem 2025, e202500138
https://doi.org/10.1002/cptc.202500138
Unlocking the reactivity of the C–In bond: alkyl indium reagents as a source of radicals under photocatalytic conditions
A. A. Gladkov, V. V. Levin, D. Y. Cheboksarov, A. D. Dilman
Chem. Sci. 2025, 16, 5623-5631
https://doi.org/10.1039/D4SC08521C
Direct C1 homologation of carboxylic acids: free radical approach enabled by acridine catalysis
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2025, 12, 2255-2259
https://doi.org/10.1039/D4QO02442G
Photocatalytic anti-Markovnikov addition of carboxylic acids to alkenes: an ionic mechanism under radical conditions
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Chem. Front. 2025, 12, 1918-1926
https://doi.org/10.1039/D4QO02280G
Light-Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Chem. Rec. 2025, 25, e202400194
https://doi.org/10.1002/tcr.202400194
Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group
A. L. Trifonov, A. D. Dilman
Org. Lett. 2024, 26, 10589–10593
https://doi.org/10.1021/acs.orglett.4c04038
Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole-Derived Sulfide Reagent
A. O. Sorokin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 5171-5175
https://doi.org/10.1002/adsc.202400884
Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids
Z. M. Rubanov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2024, 34, 673-675
https://doi.org/10.1016/j.mencom.2024.09.015
Sodium Hypophosphite as a Halogen Atom Transfer (XAT) Agent under Photocatalytic Conditions
E. V. Malakhova, V. S. Kostromitin, D. Y. Cheboksarov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 12812–12821
https://doi.org/10.1021/acs.joc.4c01412
Photoredox Activation of Fluorinated Organozinc Reagents: Hydrofluoroalkylation of Unactivated and Electron Deficient Alkenes
A. G. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2024, 89, 11826–11835
https://doi.org/10.1021/acs.joc.4c01623
Photocatalytic Functionalization of Alkenes Enabled by Polyfluoroaryl Migration
A. G. Savchenko, M. O. Zubkov, J. Hu, A. D. Dilman
ChemPhotoChem 2024, 8, e202400159
https://doi.org/10.1002/cptc.202400159
A photocatalytic method for the generation of the 1,1,1,3,3,3-hexafluoroisopropyl radical
S. S. Lunkov, V. S. Kostromitin, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 4762-4768
https://doi.org/10.1039/D4QO01023J
Photoinduced radical alkylation of aldehydes with potassium alkyltrifluoroborates
K. A. Zhilyaev, M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 3988-3996
https://doi.org/10.1039/D4QO00741G
Synthesis of N-(iminyl)pyridinium salts from hydrazones by the Zincke reaction
E. A. Ilin, V. O. Smirnov, A. D. Dilman
Russ. Chem. Bull. 2024, 73, 1297-1302
Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Org. Lett. 2024, 26, 3174–3178
https://doi.org/10.1021/acs.orglett.4c00778
Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond
M. O. Zubkov, A. D. Dilman
Chem. Soc. Rev. 2024, 53, 4741 - 4785
https://doi.org/10.1039/D3CS00889D
Tetrafluoropyridinyl Thiolate as a Tool for Enabling Photoredox Alkylation of 1,2,4-Oxadiazoles
A. E. Frumkin, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2024, 366, 3505-3510
https://doi.org/10.1002/adsc.202400075
Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion
E. V. Malakhova, V. S. Kostromitin, V. V. Levin, A. D. Dilman
Org. Chem. Front. 2024, 11, 2829-2833
https://doi.org/10.1039/D4QO00228H
Direct conversion of carboxylic acids to free thiols via radical relay acridine photocatalysis enabled by N–O bond cleavage
D. L. Lipilin, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Chem. Sci. 2024, 15, 644-650
https://doi.org/10.1039/D3SC05513B
Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides
A. A. Gladkov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 19, 3387-3391
https://doi.org/10.1002/adsc.202300757
Photocatalytic Reaction of Aryl Halides with Tin(II) Acetate to Generate Arylstannane(IV) Reagents
A. A. Zemtsov, V. I. Supranovich, V. V. Levin, A. D. Dilman
ACS Catal. 2023, 13, 12766–12773
https://doi.org/10.1021/acscatal.3c03626
C–F Activation of Fluorinated Esters Using Photocatalytically Generated Diaminoalkyl Radical
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Org. Lett. 2023, 25, 6598–6602
https://doi.org/10.1021/acs.orglett.3c02570
Zinc Chelate Complexes of N-Acyl Hydrazones as Substrates for Addition of Alkyl and Fluorinated Radicals
Z. M. Rubanov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2023, 15, 2636-2642
https://doi.org/10.1002/adsc.202300606
BF2-Chelates of N-Acylhydrazones as Versatile Coupling Partners in Photoredox Promoted Reactions
Z. M. Rubanov, V. I. Supranovich, V. V. Levin, A. D. Dilman
Eur. J. Org. Chem. 2023, 26, e202300247
https://doi.org/10.1002/ejoc.202300247
Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α-(Trifluoromethyl)styrenes
A. G. Savchenko, M. O. Zubkov, V. A. Kokorekin, J. Hu, A. D. Dilman
ChemCatChem 2023, 15, e202300505
https://doi.org/10.1002/cctc.202300505
Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine
S. L. Lunkov, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Mendeleev Commun. 2023, 33, 387–389
https://doi.org/10.1016/j.mencom.2023.04.028
Aminals as powerful XAT-reagents: activation of fluorinated alkyl chlorides
V. S. Kostromitin, A. O. Sorokin, V. V. Levin, A. D. Dilman
Chem. Sci. 2023, 14, 3229–3234
https://doi.org/10.1039/D3SC00027C
Photoredox Promoted Barbier-Type Reaction of Alkyl Iodides with N-Alkyl and N-Aryl Imines
A. A. Gladkov, V. V. Levin, A. D. Dilman
J. Org. Chem. 2023, 88, 1260–1269
https://doi.org/10.1021/acs.joc.2c02598
Light-Promoted Dearylation of Perfluorinated Aryl Sulfides with N-Heterocyclic Carbene–Borane
L. I. Panferova, M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Org. Lett. 2022, 24, 8559–8563
https://doi.org/10.1021/acs.orglett.2c03585
Novel fluorescent difluoroboryl chelate complexes derived from N-benzothiazolyl hydrazones
Z. M. Rubanov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Tetrahedron Lett. 2022, 108, 154154
https://doi.org/10.1016/j.tetlet.2022.154154
Preparation and Evaluation of Sterically Hindered Acridine Photocatalysts
K. A. Zhilyaev, D. L. Lipilin, M. D. Kosobokov, A. I. Samigullina, A. D. Dilman
Adv. Synth. Catal. 2022, 364, 3295–3301
https://doi.org/10.1002/adsc.202200515
Photocatalyzed Decarboxylative Thiolation of Carboxylic Acids Enabled by Fluorinated Disulfide
M. O. Zubkov, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Org. Lett. 2022, 24, 2354–2358
https://doi.org/10.1021/acs.orglett.2c00549
Photoredox Activation of Organozinc Reagents: Barbier-Type Reaction of Alkyl Halides with α-(Trifluoromethyl)styrenes
A. A. Gladkov, G. N. Chernov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Boron Chelates Derived from N-Acylhydrazones as Radical Acceptors: Photocatalyzed Coupling of Hydrazones with Carboxylic Acids
I. A. Dmitriev, V. V. Levin, A. D. Dilman
Photocatalytic Atom-Transfer Radical Addition of Activated Chlorides to Alkenes
V. S. Kostromitin, A. A. Zemtsov, V. V. Levin, A. D. Dilman
Adv. Synth. Catal. 2021, 363, 5336–5340
https://doi.org/10.1002/adsc.202101047
Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene
A. L. Trifonov, A. D. Dilman
One-pot synthesis of α-trifluoromethylstyrenes from aryl ketones and the Ruppert–Prakash reagent
V. V. Levin, A. D. Dilman
Radical Functionalization of Geminal Difluoroalkenes
M. O. Zubkov, M. D. Kosobokov, A. D. Dilman
Reaction of (bromodifluoromethyl)trimethylsilane with HMPA: Structural studies
V. I. Supranovich, A. D. Volodin, A. A. Korlyukov, J. Hu, A. D. Dilman
Generation of Alkyl Radicals from Thiols via Zinc Thiolates: Application for the Synthesis of gem-Difluorostyrenes
V. I. Supranovich, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Adv. Synth. Cat. 2021, 363, 2888–2892
https://doi.org/10.1002/adsc.202100088
Light-Mediated Sulfur–Boron Exchange
L. I. Panferova, A. D. Dilman
Photoredox Catalyzed Dealkylative Aromatic Halogen Substitution with Tertiary Amines
D. L. Lipilin, A. E. Frumkin, A. Y. Tyurin, V. V. Levin, A. D. Dilman
Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system
V. S. Kostromitin, A. A. Zemtsov, V. A. Kokorekin, V. V. Levin, A. D. Dilman
Chem. Commun. 2021, 57, 5219-5222
https://doi.org/10.1039/D1CC01609A
Visible-Light-Promoted Reversible Sulfide/Iodide Exchange in Fluoroalkyl Sulfides Enabled by Electron Donor-Acceptor Complex Formation
B. A. van der Worp, M. D. Kosobokov, A. D. Dilman
All-carbon phosphoranes via difluorocarbene trapping
V. O. Smirnov, A. D. Volodin, A. A. Korlyukov, A. D. Dilman
Chem. Commun. 2021, 57, 4823-4826
https://doi.org/10.1039/D1CC01075A
Photoredox Fluoroalkylation of Hydrazones in Neutral and Reductive Modes
B. A. van der Worp, M. D. Kosobokov, V. V. Levin, A. D. Dilman
Adv. Synth. Cat. 2021, 363, 1152-1158
https://doi.org/10.1002/adsc.202001381
Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent
A. A. Zemtsov, S. S. Lunkov, V. V. Levin, A. D. Dilman
Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds
L. I. Panferova, M. O. Zubkov, V. A. Kokorekin, V. V. Levin, A. D. Dilman
Angew. Chem. Int. Ed. 2021, 60, 2849–2854
https://doi.org/10.1002/anie.202011400
Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate
V. V. Levin, A. D. Dilman
Synthesis of tetrafluorinated piperidines from nitrones via a visible-light-promoted annelation reaction
V. I. Supranovich, I. A. Dmitriev, A. D. Dilman
Beilstein J. Org. Chem. 2020, 16, 3104–3108
https://doi.org/10.3762/bjoc.16.260
Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization
M. D. Kosobokov, M. O. Zubkov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Chem. Commun. 2020, 56, 9453–9456
https://doi.org/10.1039/D0CC04617E
ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping
E. A. Ilin, V. O. Smirnov, A. D. Volodin, A. A. Korlyukov, A. D. Dilman
Chem. Commun. 2020, 56, 7140–7142
https://doi.org/10.1039/D0CC02567D
Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation
A. L. Trifonov, L. I. Panferova, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Trapping of Difluorocarbene by Frustrated Lewis Pairs
V. O. Smirnov, A. D. Volodin, A. A. Korlyukov, A. D. Dilman
Angew. Chem. Int. Ed. 2020, 59, 12428–1243
https://doi.org/10.1002/anie.202001354
Photoredox Fluoroalkylation of Arylidene and Alkylidene Amidrazones
V. I. Supranovich, G. N. Chernov, V. V. Levin, A. D. Dilman
A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes
M. O. Zubkov, M. D. Kosobokov, V. V. Levin, V. A. Kokorekin, A. A. Korlyukov, J. Hu, A. D. Dilman
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
V. I. Supranovich, V. V. Levin, A. D. Dilman
Beilstein J. Org. Chem. 2020, 16, 1550-1553
https://doi.org/10.3762/bjoc.16.126
Visible-Light-Mediated Organocatalyzed Thiol-Ene Reaction Initiated by a Proton-Coupled Electron Transfer
V. V. Levin, A. D. Dilman
Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical Addition Reaction
O. V. Fedorov, S. I. Scherbinina, V. V. Levin, A. D. Dilman
Synthesis of tetrafluorinated tetrahydroquinolines via photoredox catalysis
V. I. Supranovich, A. D. Dilman
Interaction of difluoromethylene phosphobetaine with heteroatom-centered electrophiles
A. L. Trifonov, L. I. Panferova, V. V. Levin, A. D. Volodin, A. A. Korlyukov, A. D. Dilman
Photoredox Reaction of 2-Mercaptothiazolinium Salts with Silyl Enol Ethers
A. A. Zemtsov, S. S. Ashirbaev, V. V. Levin, V. A. Kokorekin, A. A. Korlyukov, A. D. Dilman
Light-mediated copper-catalyzed phosphorus/halogen exchange in 1,1-difluoroalkylphosphonium salts
L. I. Panferova, V. V. Levin, M. I. Struchkova, A. D. Dilman
Chem. Commun. 2019, 55, 1314–1317
https://doi.org/10.1039/C8CC09115C
Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light
I. A. Dmitriev, V. I. Supranovich, V. V. Levin, A. D. Dilman
Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst
V. I. Supranovich, V. V. Levin, A. D. Dilman
Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction
V. O. Smirnov, A. S. Maslov, V. A. Kokorekin, A. A. Korlyukov, A. D. Dilman
Chem. Commun. 2018, 54, 2236–2239
https://doi.org/10.1039/C8CC00245B
Photoredox mediated annelation of iododifluoromethylated alcohols with 1,1-diarylethylenes
L. I. Panferova, G. N. Chernov, V. V. Levin, V. A. Kokorekin, A. D. Dilman
Photocatalytic Reductive Fluoroalkylation of Nitrones
V. I. Supranovich, V. V. Levin, M. I. Struchkova, A. D. Dilman
Visible Light Promoted 2-Bromotetrafluoroethylation of Nitrones
I. A. Dmitriev, V. I. Supranovich, V. V. Levin, M. I. Struchkova, A. D. Dilman
Adv. Synth. Cat. 2018, 360, 3788-3792
https://doi.org/10.1002/adsc.201800802
Visible light-mediated difluoroalkylation of electron-deficient alkenes
V. I. Supranovich, V. V. Levin, M. I. Struchkova, J. Hu, A. D. Dilman
Beilstein J. Org. Chem. 2018, 14, 1637-1641
https://doi.org/10.3762/bjoc.14.139
Difluorocarbene as a Building Block for Consecutive Bond-Forming Reactions
A. D. Dilman, V. V. Levin
Reductive silylation of gem-difluorinated phosphonium salts
A. V. Tsymbal, V. V. Levin, M. I. Struchkova, V. A. Kokorekin, A. A. Korlyukov, A. D. Dilman
Light-Promoted Allylation of Iododifluoromethylated Alcohols
L. I. Panferova, M. I. Struchkova, A.D. Dilman
Synthesis of halodifluoromethyl-substituted phosphines
R. O. Iakovenko, A. D. Dilman
Dimerization of Benzyl and Allyl Halides via Photoredox-Mediated Disproportionation of Organozinc Reagents
V. V. Levin, D. P. Agababyan, M. I. Struchkova, A. D. Dilman
Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates
S. S. Ashirbaev, V. V. Levin, M. I. Struchkova, A. D. Dilman
Addition of thiols to gem-difluoroalkenes under photoactivation conditions
S. S. Ashirbaev, V. V. Levin, M. I. Struchkova, A. D. Dilman
Vinylation of Iododifluoromethylated Alcohols via a Light-Promoted Intramolecular Atom-Transfer Reaction
L. I. Panferova, M. I. Struchkova, A. D. Dilman
Radical Silyldifluoromethylation of Electron-Deficient Alkenes
V. I. Supranovich, V. V. Levin, M. I. Struchkova, A. A. Korlyukov, A. D. Dilman
Synthesis of 3-Fluoroindoles via Photoredox Catalysis
L. I. Panferova, V. O. Smirnov, V. V. Levin, V. A. Kokorekin, M. I. Struchkova, A. D. Dilman
Interaction of gem-Difluorinated Iodides with Silyl Enol Ethers Mediated by Photoredox Catalysis
G. N. Chernov, V. V. Levin, V. A. Kokorekin, M. I. Struchkova, A. D. Dilman
Adv. Synth. Cat. 2017, 359, 3063–3067
https://doi.org/10.1002/adsc.201700423
Synthesis of 3-Fluoropyridines via Photoredox-Mediated Coupling of α,α-Difluoro-β-iodoketones with Silyl Enol Ethers
S. I. Scherbinina, O. V. Fedorov, V. V. Levin, V. A. Kokorekin, M. I. Struchkova, A. D. Dilman
Difluoromethylation of Carboxylic Acids via the Addition of Difluorinated Phosphorus Ylide to Acyl Chlorides
A. L. Trifonov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Synthesis of gem-Difluorinated Hydroxypyrrolidines
O. V. Fedorov, M. I. Struchkova, A. D. Dilman
Coupling of N-acyliminium chlorides with gem-difluorinated organozinc reagents
V. V. Levin, M. I. Struchkova, A. D. Dilman
Silicon Reagent with Functionalized Tetrafluoroethylene Fragments: Preparation and Coupling with Aldehydes
O. V. Fedorov, M. I. Struchkova, A. D. Dilman
Advances in the chemistry of organozinc reagents
A. D. Dilman, V. V. Levin
Nucleophilic Difluoromethylation Using (Bromodifluoromethyl)trimethylsilane
A. L. Trifonov, A. A. Zemtsov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Synthesis of difluorosubstituted six-membered nitronates via an addition/substitution cascade
O. V. Fedorov, V. V. Levin, A. D. Volodin, M. I. Struchkova, A. A. Korlyukov, A. D. Dilman
Reactions of gem-difluoro-substituted organozinc reagents with propargyl halides
A. A. Zemtsov, N. S. Kondratyev, V. V. Levin, M. I. Struchkova, A. D. Dilman
Reactions of gem-Difluorinated Phosphonium Salts Induced by Light
L. I. Panferova, A. V. Tsymbal, V. V. Levin, M. I. Struchkova, A. D. Dilman
Dithiocarbamate-substituted gem-difluorinated silicon reagent: generation and addition to aldehydes
A. S. Maslov, V. O. Smirnov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman
Synthesis of S-difluoromethyl dithiocarbamates
V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman
Nucleophilic difluoro(trimethylsilyl)methylation of arylidene Meldrum's acids
A. D. Volodin, A. A. Zemtsov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Reactions of organozinc reagents with potassium bromodifluoroacetate
V. V. Levin, A. A. Zemtsov, M. I. Struchkova, A. D. Dilman
Reaction of gem-difluorinated organozinc reagents with β-nitrostyrenes
N. S. Kondratyev, V. V. Levin, A. A. Zemtsov, M. I. Struchkova, A. D. Dilman
Synthesis of organofluorine compounds using α-fluorine-substituted silicon reagents
A. D. Dilman, Levin, V. V.
Halogenative Difluorohomologation of Ketones
O. V. Fedorov, M. D. Kosobokov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Difluorohomologation of Ketones
M. D. Kosobokov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Coupling of α, α-difluoro-substituted organozinc reagents with 1-bromoalkynes
A. A. Zemtsov, A. D. Volodin, V. V. Levin, M. I. Struchkova, A. D. Dilman
Beilstein J. Org. Chem. 2015, 11, 2145–2149
https://doi.org/10.3762/bjoc.11.231
Nucleophilic Iododifluoromethylation of Aldehydes Using Bromine/Iodine Exchange
V. V. Levin, V. O. Smirnov, M. I. Struchkova, A. D. Dilman
Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion
V. V. Levin, A. L. Trifonov, A. A. Zemtsov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman
Nucleophilic Bromo- and Iododifluoromethylation of Aldehydes
M. D. Kosobokov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Synthesis of fluorinated 4-amino-5,6-dihydropyridin-2(1H)-ones
M. D. Kosobokov, M. I. Struchkova, A. D. Dilman
Geminal Silicon/Zinc Reagent as an Equivalent of Difluoromethylene Bis-carbanion
M. D. Kosobokov, V. V. Levin, A. A. Zemtsov, M. I. Struchkova, A. A. Korlyukov, D. E. Arkhipov, A. D. Dilman
Reactions of 1,1-difluoroalkylzinc halides with chlorinating reagents
V. O. Smirnov, A. S. Maslov, V. V. Levin, M. I. Struchkova, A. D. Dilman
Synthesis of gem-Difluorinated Nitroso Compounds
V. O. Smirnov, M. I. Struchkova, D. E. Arkhipov, A. A. Korlyukov, A. D. Dilman
J. Org. Chem. 2014, 79, 11819-11823
https://doi.org/10.1021/jo5023537
Copper-Catalyzed Allylation of α,α-Difluoro-Substituted Organozinc Reagents
A. A. Zemtsov, N. S. Kondratyev, V. V. Levin, M. I. Struchkova, A. D. Dilman
Nucleophilic Bromodifluoromethylation of Iminium Ions
A. V. Tsymbal, M. D. Kosobokov, V. V. Levin, M. I. Struchkova, A. D. Dilman
J. Org. Chem. 2014, 79, 7831–7835
https://doi.org/10.1021/jo501644m
Reactions of Difluorocarbene with Organozinc Reagents
V. V. Levin, A. A. Zemtsov, M. I. Struchkova, A. D. Dilman
Synthesis of fluorinated pyrimidinones
M. D. Kosobokov, M. I. Struchkova, D. E. Arkhipov, A. A. Korlyukov, A. D. Dilman
Nucleophilic fluoroalkylation of (bromomethyl)pinacolborane using silicon reagents
V. V. Levin, P. K. Elkin, M. I. Struchkova, A. D. Dilman
Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions
M. D. Kosobokov, A. D. Dilman, M. I. Struchkova, P. A. Belyakov, J. Hu
J. Org. Chem. 2012, 77, 2080-2086
https://doi.org/10.1021/jo202669w
Three-component reactions of CF3-substituted boranes, ethyl diazoacetate and imines
P. K. Elkin, V. V. Levin, A. D. Dilman, M. I. Struchkova, D. E. Arkhipov, A. A. Korlyukov
Nucleophilic Pentafluorophenylation of Nitroalkenes
N. S. Kondratyev, A. A. Zemtsov, V. V. Levin, A. D. Dilman, M. I. Struchkova
Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
M. D. Kosobokov, A. D. Dilman, V. V. Levin, M. I. Struchkova
J. Org. Chem. 2012, 77, 5850-585
https://doi.org/10.1021/jo301094b
Reactions of CF3-substituted boranes with α-diazocarbonyl compounds
P. K. Elkin, V. V. Levin, A. D. Dilman, M. I. Struchkova, P. A. Belyakov, D. E. Arkhipov, A. A. Korlyukov, V. A. Tartakovsky
Nucleophilic trifluoromethylation with organoboron reagents
V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Nucleophilic Trifluoromethylation of C=N Bonds
A. D. Dilman, V. V. Levin
Reactions of fluorinated silanes with 2-nitrocinnamates
A. A. Zemtsov, V. V. Levin, A. D. Dilman, M. I. Struchkova, V. A. Tartakovsky
Reaction of Baylis–Hillman Adducts with Fluorinated Silanes
A. A. Zemtsov, V. V. Levin, A. D. Dilman, M. I. Struchkova, P. A. Belyakov, V. A. Tartakovsky, J. Hu
Synthesis of CF3-substituted 1,2,3,4-tetrahydroisoquinolines and 1,2,3,6-tetrahydropyridines
I. Yu. Chernyshov,V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Fluorocyanation of Enamines
A. D. Dilman, P. A. Belyakov, M. I. Struchkova, D. E. Arkhipov, A. A. Korlyukov, V. A. Tartakovsky
J. Org. Chem. 2010, 75, 5367-5370
https://doi.org/10.1021/jo1008993
Chelation-assisted pentafluorophenylation of oximes
V. V. Levin, R. T. Gritsenko, A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, D. E. Arkhipov, M. I. Struchkova, V. A. Tartakovsky
Hydroxyl-directed trifluoromethylation of hydrazones
A. D. Dilman, V. V. Levin, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
Nucleophilic trifluoromethylation of arylidene Meldrum's acids
A. A. Zemtsov, V. V. Levin, A. D. Dilman, M. I. Struchkova, P. A. Belyakov, V. A. Tartakovsky
Trifluoromethylation of enamines under acidic conditions
R. T. Gritsenko, V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Reaction of the Ruppert-Prakash reagent with perfluorosulfonic acids
V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Trifluoromethylation of the amide group
V. V. Levin, M. A. Kozlov, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Russ. Chem. Bull., Int. Ed., 2009, 58, 484-486
https://doi.org/10.1007/s11172-010-0039-x
Nucleophilic trifluoromethylation of arylidenemalononitriles
A. D. Dilman, V. V. Levin, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Nucleophilic fluoroalkylation of iminium salts
V. V. Levin, M. A. Kozlov, Y.-H. Song, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Nucleophilic Trifluoromethylation of Imines under Acidic Conditions
V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Complexation of tris(pentafluorophenyl)silanes with neutral Lewis bases
A. D. Dilman, V. V. Levin, A. A. Korlyukov, P. A. Belyakov, M. I. Struchkova, M. Yu. Antipin, V. A. Tartakovsky
Trifluoromethylation of N-Benzoylhydrazones
A. D. Dilman, D. E. Arkhipov, V. V. Levin, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
Reaction of Formamides with Fluorotris(pentafluorophenyl)silane
V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova
Trifluoromethylation of Salicyl Aldimines
A. D. Dilman, D. E. Arkhipov, V. V. Levin, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
Trifluoromethylation and pentafluorophenylation of enamines
A. D. Dilman, V. V. Gorokhov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Synthesis of C6F5-substituted amines containing quaternary carbon atoms
A. D. Dilman, V. V. Levin, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Activation of pentafluorophenylsilanes by weak Lewis bases in reaction with iminium cations
A. D. Dilman, V. V. Levin, M. Karni, Y. Apeloig
Pentafluorophenyltrifluorosilane in the silicon Mannich reaction
A. D. Dilman, V. V. Gorokhov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Synthesis of C6F5-Substituted Aminoethanols via Acetate Ion Mediated C6F5-Group Transfer Reaction
V. V. Levin, A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, M. Y. Antipin, V. A. Tartakovsky
Chloride ion promoted nucleophilic pentafluorophenylation of imines
V. V. Levin, A. D. Dilman, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
Pentafluorophenylation of -aminoacrylates
V. V. Levin, A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
A. D. Dilman, D. E. Arkhipov, A. A. Korlyukov, V. P. Ananikov, V. M. Danilenko, V. A. Tartakovsky
Synthesis of pentafluorophenylmethylamines via silicon Mannich reaction
A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
On the interaction of silyl triflates with enamines: iminium ion formation vs. silylation
V. V. Levin, A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
Tris(pentafluorophenyl)silyl triflate: synthesis and silylation of carbonyl compounds
A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, V. A. Tartakovsky
Tris(pentafluorophenyl)silyl enol ethers: synthesis and aldol reactions
V. V. Levin, A. D. Dilman, P. A. Belyakov, A. A. Korlyukov, M. I. Struchkova, V. A. Tartakovsky
New approach for the synthesis of isoxazoline-N-oxides
R. A. Kunetsky, A. D. Dilman, S. L. Ioffe, M. I. Struchkova, Y. A. Strelenko, V. A. Tartakovsky
Org. Lett. 2003, 5, 4907-4909
A New Strategy for the Synthesis of γ-Nitro Alcohols from Aliphatic Nitro Compounds
R. A. Kunetsky, A. D. Dilman, K. P. Tsvaygboym, S. L. Ioffe, Yu. A. Strelenko, V. A. Tartakovsky
Synthesis, 2003, 1339-1346
Reactions of N,N-bis(silyloxy)enamines with sulfur-centered and sulfur-stabilised electrophiles
A. V. Ustinov, A. D. Dilman, S. L. Ioffe, Yu. A. Strelenko, W. A. Smit, V. A. Tartakovsky
Mendeleev Commun., 2003, 74-76
Carbon-carbon bond forming reactions mediated by silicon Lewis acids
A. D. Dilman, S. L. Ioffe
Chem. Rev. 2003, 103, 733-772
Химия N,N-бис(силилокси)енаминов. Сообщение 4. Изучение реакций N,N-бис(силилокси)енаминов с 1,3-дикарбонильными соединениями
А. В. Устинов, А. Д. Дильман, С. Л. Иоффе, П. А. Беляков, Ю. А. Стреленко
Изв. Акад. Наук., Сер. хим., 2002, 1343
Structure and stereodynamics of N,N-bis(silyloxy)enamines
A. A. Tishkov, A. D. Dilman, V. I. Faustov, A. A. Birukov, K. S. Lysenko, P. A. Belyakov, S. L. Ioffe, Yu. A. Strelenko, M. Yu. Antipin
J. Am. Chem. Soc., 2002, 124, 11358-11367
Силилирование как новая стратегия использования алифтических нитросоединений в органическом синтезе
В. А. Тартаковский, С. Л. Иоффе, А. Д. Дильман, А. А. Тишков
Изв. Акад. Наук., Сер. хим., 2001, 1850–1859
Determination of the nucleophilicities of N,N-bis(silyloxy)enamines
A. D. Dilman, S. L. Ioffe, H. Mayr
J. Org. Chem., 2001, 66, 3196–3200
Chemistry of N,N-bis(silyloxy)enamines. 3. N,N-Bis(silyloxy)enamines as β-C-nucleophiles in reaction with acetals mediated by trimethylsilyl trifluoromethanesulfonate
A. D. Dilman, I. M. Lyapkalo, S. L. Ioffe, Yu. A. Strelenko, V. A. Tartakovsky
J. Org. Chem., 2000, 65, 8826–8829
Synthesis of N,N-bis(silyloxy)enamines with functionalized double bond
A. D. Dilman, A. A. Tishkov, I. M. Lyapkalo, S. L. Ioffe, V. V. Kachala, Yu. A. Strelenko, V. A. Tartakovsky
J. Chem. Soc. Perkin Trans. 1, 2000, 2926–2929
Триметилсилильные производные алифатических нитросоединений в реакции α,β-C,C-кросс-сочетания
А. Д. Дильман, И. М. Ляпкало, С. Л. Иоффе, Ю. А. Стреленко, В. А. Тартаковский
Изв. Акад. Наук., Сер. хим., 2000, 876–880
N,N-Бис(трет-бутилдиметилсилилокси)аминобензол как новый синтетический эквивалент нитрозобензола
А. Д. Дильман, И. М. Ляпкало, П. А. Беляков, С. Л. Иоффе, Ю. А. Стреленко, В. А. Тартаковский
Изв. Акад. Наук., Сер. хим., 2000, 1659–1660
Chemistry of N,N-Bis(silyloxy)enamines. 1. Novel convenient method for the synthesis of β–nitro oximes by C,C-cross-coupling of terminal N,N-bis(silyloxy)enamines with nitronate anions
A. D. Dilman, I. M. Lyapkalo, S. L. Ioffe, Yu. A. Strelenko, V. A. Tartakovsky
Synthesis, 1999, 1767–1775
Взаимодействие нитронатов — производных нитроалканов — с некоторыми тиостабилизированными катионоидными интермедиатами
И. М. Ляпкало, М. И. Лазарева, А. Д. Дильман, С. Л. Иоффе, В. А. Смит
Изв. Акад. Наук., Сер. хим., 1999, 492–497
Тетраметилсилан как газ-реагент: масс-спектры эфиров нитрокарбоновых кислот и нитроспиртов
В. И. Каденцев, Н. Г. Колотыркина, А. А. Стомахин, О. С. Чижов, С. Л. Иоффе, И. М. Ляпкало, А. Д. Дильман, А. А. Тишков
Изв. Акад. Наук., Сер. хим., 1998, 1257–1259
Четырехкомпонентное сочетание по схеме последовательности AdE-реакций с участием аренсульфенилхлорида, двух алкилвиниловых эфиров и кремнийорганических π-доноров как метод получения полифункциональных соединений
М. И. Лазарева, Ю. К. Крыщенко, А. Д. Дильман, А. Хейфорд, Р. Кэйпл, В. А. Смит
Изв. Акад. Наук., Сер. хим., 1998, 924–932
Novel Convenient Method for the Synthesis of N,N-bis(trimethylsilyloxy)enamines
A. D. Dilman, A. A. Tishkov, I. M. Lyapkalo, S. L. Ioffe, Yu. A. Strelenko, V. A. Tartakovsky
Synthesis, 1998, 181–185
Trimethylsilyl derivatives of aliphatic nitro compounds in α,β-C,C-cross-coupling reactions
A. D. Dilman, I. M. Lyapkalo, Yu. A. Strelenko, S. L. Ioffe, V. A. Tartakovsky
Mendeleev Commun., 1997, 133–135
Trimethylsilyl Derivatives as Final Nucleophiles in the Tandem Sequence of an ArSCl Initiated AdE Reaction Resulting in the Synthesis of Polyfunctional Compounds
A. Hayford, M. Lovdahl, M. I. Lazareva, Yu. K. Kryschenko, T. Johnson, A. D. Dilman, I. P. Smoliakova, R. Caple, W. A. Smit
Mendeleev Commun., 1997, 48–50
Синтез аномально устойчивого C-метоксикарбонил-N-(п-нитрофенил)нитрона
А. Д. Дильман, И. М. Ляпкало, С. Л. Иоффе, Ю. А. Стреленко, В. А. Тартаковский
Ж. Орг. Хим. 1996, 36, 463–464